Physical properties of metals and non-metals
Metals are usually lustrous (shiny), hard, malleable (can be beaten into sheets), ductile (can be drawn into wires), sonorous (ring when struck) and good conductors of heat and electricity. Silver and copper are the best conductors; lead and mercury are rather poor ones.
Non-metals are usually dull, brittle, non-sonorous and poor conductors. Many are gases (oxygen, nitrogen, chlorine) or soft solids (sulphur, phosphorus); bromine is a liquid.
Exceptions students are asked about
- Mercury is a metal but liquid at room temperature.
- Sodium and potassium are metals soft enough to cut with a knife and have low melting points; gallium and caesium melt on a warm palm.
- Iodine is a non-metal but shiny.
- Carbon as diamond is the hardest natural substance; carbon as graphite conducts electricity.
Chemical properties: reaction of metals with oxygen
Most metals join with oxygen to make metal oxides, which are basic: e.g. 2Mg + O2 → 2MgO. Soluble basic oxides (Na2O, K2O) dissolve in water to form alkalis.
Some oxides such as Al2O3 and ZnO react with both acids and bases; they are amphoteric oxides. Al2O3 + 6HCl → 2AlCl3 + 3H2O and Al2O3 + 2NaOH → 2NaAlO2 + H2O.
Different metals react differently: sodium and potassium catch fire in open air, so they are stored under kerosene; magnesium burns brightly when heated; iron only burns as fine filings; copper just forms a black CuO layer; silver and gold do not react even when hot. Non-metals form acidic or neutral oxides (SO2, CO2 are acidic; CO, N2O are neutral).
Reaction of metals with water
Metal + water → metal hydroxide (or oxide) + hydrogen.
- Sodium and potassium react violently with cold water; the heat can set the hydrogen alight. 2Na + 2H2O → 2NaOH + H2.
- Calcium reacts less violently; bubbles stick to it so it floats.
- Magnesium reacts with hot water (and also floats).
- Aluminium, zinc and iron react only with steam, giving the oxide: 3Fe + 4H2O(steam) → Fe3O4 + 4H2.
- Lead, copper, silver and gold do not react with water at all.
Reaction of metals with dilute acids
Metal + dilute acid → salt + hydrogen, e.g. Zn + 2HCl → ZnCl2 + H2. The fizzing is fastest for Mg, then Al, Zn, Fe. Copper gives no hydrogen with dilute HCl.
With nitric acid, hydrogen is usually not given off, because HNO3 is a strong oxidising agent that turns the hydrogen into water. Only magnesium and manganese give H2 with very dilute nitric acid. Aqua regia (3 parts conc. HCl : 1 part conc. HNO3) can dissolve gold and platinum.
Reaction of metals with salt solutions (displacement)
A more reactive metal pushes a less reactive metal out of its salt solution: Fe + CuSO4 → FeSO4 + Cu. The blue solution turns pale green and a brown copper layer forms on the nail. Copper cannot push iron out of FeSO4, so nothing happens the other way round.
The reactivity series
Arranging metals in decreasing order of reactivity gives the reactivity series: K > Na > Ca > Mg > Al > Zn > Fe > Pb > [H] > Cu > Hg > Ag > Au.
- Metals above hydrogen give H2 with dilute acids; those below do not.
- A metal can displace any metal below it from its salt solution.
- The position also decides how the metal is extracted (see the lesson on extraction).
Board exams often ask you to predict a displacement, arrange metals from given observations, or explain why copper does not react with dilute HCl (usually 2–3 marks).
Key formulas and definitions
- Metal + oxygen → metal oxide (basic; Al₂O₃ and ZnO amphoteric)
- Metal + water → metal hydroxide/oxide + H₂
- Metal + dilute acid → salt + H₂ (only metals above H)
- Metal A + salt of metal B → salt of A + metal B (if A is above B)
- Reactivity series: K > Na > Ca > Mg > Al > Zn > Fe > Pb > H > Cu > Hg > Ag > Au
Worked examples
1. Why is sodium kept under kerosene?
Sodium reacts very fast with oxygen and moisture in air and can catch fire. Kerosene does not react with sodium and keeps air and water away.
2. Write the balanced equation for zinc with dilute sulphuric acid and name the gas.
Zn + H₂SO₄ → ZnSO₄ + H₂. The gas is hydrogen; it burns with a pop sound when a lit splinter is brought near.
3. Show that aluminium oxide is amphoteric.
With acid: Al₂O₃ + 6HCl → 2AlCl₃ + 3H₂O (acts as a base). With base: Al₂O₃ + 2NaOH → 2NaAlO₂ + H₂O (acts as an acid). Reacting with both makes it amphoteric.
4. Metal X displaces copper from CuSO₄ but not zinc from ZnSO₄. Place X in the reactivity series.
X is above Cu (it displaces Cu) but below Zn (it cannot displace Zn). So Zn > X > Cu; X could be iron or lead.
5. Silver in silver nitrate, copper strip dipped in. What do you see and why?
Copper is above silver, so Cu + 2AgNO₃ → Cu(NO₃)₂ + 2Ag. Shiny grey silver crystals form on the copper and the solution slowly turns blue.
Common mistakes
- Saying all metals are solids: mercury is a liquid metal.
- Thinking every metal gives hydrogen with acid: copper, silver and gold (below H) do not.
- Writing that metals give hydrogen with nitric acid: HNO₃ oxidises the H₂ to water (except Mg and Mn with very dilute acid).
- Reversing displacement: a lower metal can never push out a higher one, e.g. Cu + FeSO₄ → no reaction.