The three particles inside an atom
Protons carry a positive charge (+1) and sit in the nucleus. Neutrons have no charge and also sit in the nucleus. Electrons carry a negative charge (−1), have almost no mass (about 1/1836 of a proton) and move around the nucleus.
An atom has equal numbers of protons and electrons, so overall it is neutral.
How the atomic model developed
Thomson (1897) found the electron and pictured the atom as a positive sphere with electrons stuck in it. Rutherford (1911) fired alpha particles at gold foil; a few bounced back, which showed that the positive charge and mass sit in a tiny nucleus. Bohr (1913) proposed that electrons move only in fixed shells with fixed energies. Chadwick (1932) discovered the neutron.
Atomic number and mass number
The atomic number (Z) is the number of protons; it decides which element the atom is. The mass number (A) is protons + neutrons. Atoms of the same element with different numbers of neutrons are isotopes, for example carbon-12 and carbon-14.
Electron shells (K, L, M, N)
A shell n can hold at most 2n² electrons: K holds 2, L holds 8, M holds 18. In the 2-8-8 scheme used in school, sodium (11 electrons) is 2, 8, 1. The electrons in the outer shell are the valence electrons, and they decide how the atom reacts. Rotate the 3D model and pick an element to see its shells.
Key formulas and definitions
- Atomic number Z = number of protons
- Mass number A = protons + neutrons
- Neutrons = A − Z
- Maximum electrons in shell n = 2n²
Worked examples
1. Chlorine has Z = 17 and A = 35. How many protons, neutrons and electrons does it have?
Protons = 17, electrons = 17, neutrons = 35 − 17 = 18.
2. Write the electron distribution of oxygen (Z = 8).
K = 2, L = 6, so 2, 6. It has 6 valence electrons.
3. What is the valency of magnesium (Z = 12)?
Distribution 2, 8, 2. It loses its 2 outer electrons, so valency = 2.
Common mistakes
- Mixing up atomic number and mass number. Z counts protons only; A counts protons and neutrons.
- Thinking electrons are in the nucleus.
- Filling more than 8 electrons in the outer shell for the first 20 elements.
- Thinking isotopes have different numbers of protons. They differ only in neutrons.