The main classes of inorganic substances
A simple substance has one kind of atom: a metal (Ca, Na, Mg) or a non-metal (C, S, O2).
A compound has two or more kinds of atoms. The main classes are:
- Oxides: an element joined with oxygen (CaO, CO2). Basic oxides come from metals, acidic oxides come from non-metals.
- Bases: a metal with OH groups (NaOH, Ca(OH)2). A base that dissolves in water is called an alkali.
- Acids: hydrogen that can be given away, joined to an acid part (HCl, H2SO4).
- Salts: a metal part and an acid part (NaCl, CaCO3).
What is a genetic link?
"Genetic" here does not mean genes. It means born from. A genetic link says: this substance can be made from that one. Write them in a row and you get a genetic series.
Metal series: Ca โ CaO โ Ca(OH)2 โ CaCO3
Non-metal series: C โ CO2 โ H2CO3 โ CaCO3
Notice that the two series meet in a salt.
Step by step: the equations
- Metal + oxygen โ basic oxide: 2Ca + O2 โ 2CaO
- Basic oxide + water โ base: CaO + H2O โ Ca(OH)2
- Non-metal + oxygen โ acidic oxide: C + O2 โ CO2
- Acidic oxide + water โ acid: CO2 + H2O โ H2CO3
- Base + acid โ salt + water: Ca(OH)2 + H2CO3 โ CaCO3 + 2H2O
Shortcuts also exist: basic oxide + acid โ salt + water, and base + acidic oxide โ salt + water. Only metals that give a base soluble in water (like Na, K, Ca) can use the water step; for others (like Cu) the base is made from a salt with an alkali.
Other ways to reach a salt
A salt can also be made by: metal + acid (Zn + 2HCl โ ZnCl2 + H2), metal + non-metal (2Na + Cl2 โ 2NaCl), or salt + salt in solution (a new salt appears when one product is insoluble). Each is one more link in the web.
Organic and inorganic are linked too
Organic compounds are built on carbon chains: hydrocarbons, alcohols, acids, sugars, and so on. They are not a separate world. Burn any of them and you get inorganic CO2 and H2O. Plants do the reverse in photosynthesis: 6CO2 + 6H2O โ C6H12O6 + 6O2. Carbon keeps moving between living and non-living things.
Key formulas and definitions
- Metal + Oโ โ basic oxide
- Basic oxide + HโO โ base
- Non-metal + Oโ โ acidic oxide
- Acidic oxide + HโO โ acid
- Base + acid โ salt + water
- Organic matter + Oโ โ COโ + HโO (burning); COโ + HโO โ sugar + Oโ (plants)
Worked examples
1. Write the genetic series of sodium to sodium sulfate.
Na โ Na2O โ NaOH โ Na2SO4. Steps: 4Na + O2 โ 2Na2O; Na2O + H2O โ 2NaOH; 2NaOH + H2SO4 โ Na2SO4 + 2H2O.
2. Write the series of sulfur to sulfuric acid.
S โ SO2 โ SO3 โ H2SO4. S + O2 โ SO2; 2SO2 + O2 โ 2SO3; SO3 + H2O โ H2SO4.
3. Which two substances give calcium sulfate in one step?
Calcium hydroxide and sulfuric acid: Ca(OH)2 + H2SO4 โ CaSO4 + 2H2O. Also CaO + H2SO4 โ CaSO4 + H2O.
4. Burning 12 g of carbon fully gives how much CO2? (C = 12, O = 16)
C + O2 โ CO2. 12 g C is 1 mole, giving 1 mole CO2 = 44 g.
5. Complete the chain: Mg โ ? โ Mg(OH)2 โ MgCl2
Mg โ MgO โ Mg(OH)2 โ MgCl2. 2Mg + O2 โ 2MgO; MgO + H2O โ Mg(OH)2 (slowly); Mg(OH)2 + 2HCl โ MgCl2 + 2H2O.
6. Copper oxide does not react with water. How do we reach Cu(OH)2 from CuO?
Go through a salt: CuO + 2HCl โ CuCl2 + H2O, then CuCl2 + 2NaOH โ Cu(OH)2 (blue solid) + 2NaCl.
Common mistakes
- Thinking every oxide reacts with water. CuO and SiO2 do not, so their base or acid is made another way.
- Writing a salt formula with wrong charges, like NaSO4. Balance charges: Na2SO4.
- Mixing the sides: a metal oxide gives a base, a non-metal oxide gives an acid, not the other way round.
- Forgetting that water forms when a base meets an acid. Salt alone is not the whole answer.