Heat, temperature and internal energy
Temperature tells how hot something is. It is measured in °C or K. Heat is energy that moves from a hotter body to a colder body. It is measured in joules (J).
The particles in a body always move. The total energy of these moving particles is its internal energy. Heating a body gives it more internal energy, so its particles move faster and its temperature goes up.
A big bucket of warm water can hold more heat than a small cup of boiling water. So temperature and heat are not the same thing.
What is specific heat capacity?
Specific heat capacity (c) is the energy needed to raise the temperature of 1 kg of a material by 1 °C (1 K is the same step).
Unit: J/(kg·°C) or J/(kg·K).
Typical values
- Water: about 4200 J/(kg·°C)
- Ice: about 2100
- Cooking oil: about 2000
- Aluminium: about 900
- Iron / steel: about 450
- Copper: about 390
A large c means the material needs lots of energy to warm up, and it gives out lots of energy as it cools. A small c means it heats up and cools down quickly. Metal pans have a small c, so they heat fast.
Heat capacity (without "specific") is for a whole object: C = m × c, in J/°C.
The quantity of heat: Q = mcΔT
The heat Q needed (or given out) depends on three things:
- the mass m (more stuff needs more energy),
- the material, through c,
- the temperature change ΔT = final − initial.
Q = m × c × ΔT
Use m in kg, c in J/(kg·°C) and ΔT in °C to get Q in J. If ΔT is negative, the body gives out heat as it cools.
Rearranged: c = Q ÷ (mΔT), m = Q ÷ (cΔT), ΔT = Q ÷ (mc).
Heat balance and calorimetry
When a hot body and a cold body touch, heat flows from hot to cold until both reach the same temperature (thermal equilibrium). If no heat escapes to the air:
Heat given by the hot body = heat taken by the cold body
m₁c₁(T₁ − T) = m₂c₂(T − T₂), where T is the final temperature.
This is just conservation of energy. A calorimeter is an insulated cup (often copper or aluminium, with a lid, a stirrer and a thermometer) used to do such mixing with very little heat loss.
Measuring c with a heater
Put an electric heater of known power P into a block of mass m for time t. The energy is Q = P × t. Measure the temperature rise and use c = Pt ÷ (mΔT). Real results come out a bit high because some heat escapes; insulation reduces this error.
Where a high c helps
Water in car radiators and in home heating, hot-water bottles, sea breezes and the mild climate near oceans all depend on water's large c.
Key formulas and definitions
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Worked examples
1. How much energy heats 2 kg of water from 20 °C to 30 °C? (c = 4200 J/(kg·°C))
ΔT = 30 − 20 = 10 °C. Q = mcΔT = 2 × 4200 × 10 = 84 000 J = 84 kJ.
2. A 0.5 kg iron block (c = 450 J/(kg·°C)) cools from 100 °C to 40 °C. How much heat does it give out?
ΔT = 60 °C. Q = 0.5 × 450 × 60 = 13 500 J = 13.5 kJ given out.
3. 18 000 J warms 2 kg of a metal by 10 °C. Find c.
c = Q ÷ (mΔT) = 18 000 ÷ (2 × 10) = 900 J/(kg·°C). This is close to aluminium.
4. A 1 kW kettle runs for 84 s and heats 0.5 kg of water. Find the temperature rise (no heat loss).
Q = Pt = 1000 × 84 = 84 000 J. ΔT = Q ÷ (mc) = 84 000 ÷ (0.5 × 4200) = 40 °C.
5. 0.2 kg of water at 80 °C is mixed with 0.3 kg of water at 20 °C. Find the final temperature.
Heat lost = heat gained: 0.2 × 4200 × (80 − T) = 0.3 × 4200 × (T − 20). c cancels: 16 − 0.2T = 0.3T − 6, so 0.5T = 22, T = 44 °C.
6. A 0.1 kg copper ball (c = 390) at 200 °C is dropped into 0.39 kg of water at 20 °C. Find the final temperature (ignore the cup).
Heat lost by copper = 0.1 × 390 × (200 − T) = 39(200 − T). Heat gained by water = 0.39 × 4200 × (T − 20) = 1638(T − 20). So 7800 − 39T = 1638T − 32 760, 1677T = 40 560, T ≈ 24.2 °C. The water hardly warms because its c is so large.
Common mistakes
- Using grams instead of kilograms with c in J/(kg·°C): 250 g must be written as 0.25 kg.
- Taking ΔT as the final temperature. ΔT is the change: final − initial.
- Thinking heat and temperature are the same. A spark is very hot but carries very little heat.
- In mixing problems, writing heat lost = heat gained but forgetting to include the container (calorimeter) when its mass and c are given.