Three ways heat travels
- Conduction: heat passes between neighbouring particles by collisions and vibrations. The particles stay in place. Main mode in solids. In metals, free electrons carry heat fast, which is why metals are good conductors.
- Convection: the fluid itself moves and carries heat. Heated fluid expands, becomes less dense and rises (buoyancy); cooler fluid sinks. This is natural convection. If a fan or pump pushes the fluid, it is forced convection (car radiator, human blood). Examples: sea breeze by day, land breeze by night; trade winds.
- Radiation: heat carried by electromagnetic waves (mostly infrared). Needs no medium and travels at the speed of light. This is how the Sun heats the Earth.
Thermal conductivity
In steady state, heat flows through a bar of length L and cross-section A, with ends at T₁ and T₂ (T₁ > T₂), at the rate:
H = k A (T₁ − T₂) / L
H is in watts (J/s). k is the coefficient of thermal conductivity, unit W m⁻¹ K⁻¹. Values: silver ≈ 406, copper ≈ 385, aluminium ≈ 205, steel ≈ 50, glass ≈ 0.8, water ≈ 0.6, wood ≈ 0.12, air ≈ 0.024.
Thermal resistance R = L/(kA), so H = ΔT/R, just like I = V/R in electricity. Slabs one after another (in series) add: R = R₁ + R₂. Side by side (in parallel): 1/R = 1/R₁ + 1/R₂.
Uses: cooking pots have copper bottoms (spread heat fast); thermos flasks and double glass windows trap air (poor conductor); igloos keep Inuit warm because snow traps air.
Radiation and the blackbody
Every body above 0 K radiates energy. How much depends on its temperature and surface. Dark, rough surfaces absorb and emit well; shiny, white surfaces reflect and emit poorly. A good absorber is also a good emitter (Kirchhoff's idea).
A blackbody absorbs all radiation falling on it and reflects none. It is also the best possible emitter. A small hole in a hollow box with blackened walls acts almost like a perfect blackbody.
The radiation from a blackbody spreads over many wavelengths, with a peak at λm. As the body gets hotter, the whole curve rises and the peak shifts to shorter wavelengths. That is why an iron rod in a furnace glows dull red, then orange, then yellow-white.
Wien's displacement law
λm T = b, where b = 2.9 × 10⁻³ m K (Wien's constant). Hotter body ⇒ shorter peak wavelength.
The Sun's spectrum peaks near 500 nm, so its surface temperature is about 2.9 × 10⁻³ / 500 × 10⁻⁹ ≈ 5800 K. The human body (310 K) peaks near 9400 nm, in the infrared; thermal cameras see this.
Stefan–Boltzmann law
Total power radiated by a blackbody of area A at absolute temperature T:
P = σ A T⁴, σ = 5.67 × 10⁻⁸ W m⁻² K⁻⁴
For a real body, P = e σ A T⁴, where the emissivity e is between 0 and 1 (e = 1 for a blackbody). If the body is at T in surroundings at T₀, the net power lost is P = e σ A (T⁴ − T₀⁴).
Because of T⁴, doubling the temperature makes the radiated power 16 times. The greenhouse effect: the Earth re-radiates in the infrared; gases like CO₂ and water vapour absorb some of it and send it back, keeping the Earth warm.
Newton's law of cooling
For small temperature differences, the rate of cooling of a body is proportional to how much hotter it is than its surroundings:
−dT/dt = K (T − Ts)
So hot tea cools fast at first and slowly later. A useful average form: (T₁ − T₂)/t = K[(T₁ + T₂)/2 − Ts]. The graph of ln(T − Ts) against time is a straight line with negative slope.
Try it: two spoons and an ink drop
1) Stand a steel spoon and a wooden spoon in hot tea. After a minute, feel the handles: steel is warm (good conductor), wood is cool. 2) Drop one drop of ink at the bottom edge of a glass of warm water held over a candle-warm spot (ask an adult): the ink rises in the middle and sinks at the sides. 3) In the 3D, step 6, put T = 3000 K, note λmax, then set 6000 K. λmax should halve.
Key formulas and definitions
- H = k A (T₁ − T₂) / L (W)
- Thermal resistance R = L / (kA); H = ΔT / R
- Series: R = R₁ + R₂; parallel: 1/R = 1/R₁ + 1/R₂
- Wien: λm T = b = 2.9 × 10⁻³ m K
- Stefan: P = e σ A T⁴; σ = 5.67 × 10⁻⁸ W m⁻² K⁻⁴
- Net loss: P = e σ A (T⁴ − T₀⁴)
- Newton's cooling: −dT/dt = K (T − Ts)
Worked examples
1. A copper rod 0.5 m long, area 1 × 10⁻⁴ m², has ends at 100 °C and 0 °C. Find the heat flow rate. (k = 385 W/m K)
Step 1: H = kAΔT/L. Step 2: = 385 × 10⁻⁴ × 100 / 0.5. Answer: 7.7 W.
2. A glass window pane is 1 m × 1 m, 4 mm thick. Inside 25 °C, outside 5 °C. Find heat lost per second. (k = 0.8 W/m K)
Step 1: ΔT = 20 K, L = 0.004 m. Step 2: H = 0.8 × 1 × 20 / 0.004. Answer: 4000 W. That is why double glazing (with air between) is used in cold places.
3. The Sun's radiation peaks at 480 nm. Estimate its surface temperature. (b = 2.9 × 10⁻³ m K)
Step 1: T = b/λm. Step 2: = 2.9 × 10⁻³ / 480 × 10⁻⁹. Answer: T ≈ 6040 K.
4. A blackbody at 1000 K emits power P. What does it emit at 2000 K?
Step 1: P ∝ T⁴. Step 2: ratio = (2000/1000)⁴ = 16. Answer: 16P.
5. Find the power radiated by a blackbody sphere of area 0.01 m² at 1000 K. (σ = 5.67 × 10⁻⁸)
Step 1: P = σAT⁴. Step 2: T⁴ = 10¹². Step 3: P = 5.67 × 10⁻⁸ × 0.01 × 10¹². Answer: 5670 W.
6. Two slabs of equal area are joined in series: copper (k = 385, L = 1 cm) and steel (k = 50, L = 1 cm). The outer faces are at 100 °C and 0 °C. Find the junction temperature.
Step 1: Same H through both: k₁(100 − T)/L = k₂(T − 0)/L. Step 2: 385(100 − T) = 50T. Step 3: 38500 = 435T. Answer: T ≈ 88.5 °C. Most of the temperature drop is across the poor conductor (steel).
7. A cup of tea cools from 80 °C to 60 °C in 5 minutes in a room at 20 °C. How long will it take to cool from 60 °C to 40 °C? (use the average form of Newton's law)
Step 1: First interval: (80 − 60)/5 = K(70 − 20) ⇒ 4 = 50K ⇒ K = 0.08 per min. Step 2: Second: (60 − 40)/t = 0.08 × (50 − 20) = 2.4. Step 3: t = 20/2.4. Answer: t ≈ 8.3 min. It cools more slowly as it nears room temperature.
Common mistakes
- Thinking particles travel along the rod in conduction. They only vibrate in place and pass energy on.
- Using °C in Stefan's law. T must be in kelvin, since P ∝ T⁴.
- Thinking heat rises. Hot fluid rises (it is less dense); heat itself can flow in any direction.
- Forgetting that a good absorber is also a good emitter. A black kettle cools faster than a shiny one.