What is emf?
A cell has two electrodes in an electrolyte. Chemical reactions push positive charge to one electrode and negative to the other. The cell does work to move charge against the field inside it, like a pump lifting water.
emf (ε) = work done by the cell per unit charge in taking it once round the complete circuit. Unit: volt. emf is not a force, despite the old name 'electromotive force'.
emf equals the potential difference across the terminals when no current flows (open circuit).
Internal resistance and terminal voltage
Current must also flow through the electrolyte inside the cell. The electrolyte resists it: this is the internal resistance r.
- Total resistance in the loop = R + r
- Current: I = ε /(R + r)
- Voltage used inside the cell = Ir
- Terminal voltage: V = ε − Ir = IR
So V < ε while the cell gives current. When the cell is being charged (current forced in the other way), V = ε + Ir, more than ε.
Finding r: r = (ε/V − 1) R = (ε − V)/I.
r depends on the electrolyte, the distance between plates, their area and the age of the cell.
emf versus potential difference
- emf is the cause (energy given per coulomb by the source); potential difference is the effect (energy used per coulomb between two points).
- emf exists even with no current; potential difference across a resistor exists only when current flows.
- emf is a property of the source; potential difference can be between any two points of a circuit.
- For a discharging cell, terminal p.d. is less than emf.
Electrical energy and power
When charge q moves through a potential drop V, the energy given is W = qV = VIt. Power P = W/t = VI.
For a resistor, using V = IR: P = I²R = V²/R. This becomes heat (Joule heating).
Energy bills use the kilowatt hour: 1 kWh = 1000 W × 3600 s = 3.6 × 10⁶ J (one 'unit').
Power in a whole circuit: the cell supplies εI. Of this, I²R goes to R and I²r is lost inside: εI = I²R + I²r.
Maximum power: P = ε²R/(R + r)². This is largest when R = r, and then Pmax = ε²/4r (efficiency only 50%).
Why power lines use high voltage: for the same power P = VI, higher V means smaller I, so the loss I²Rline in the cables becomes much smaller.
Cells in series
Join + of one cell to − of the next. The same current flows through both.
- Potential rises: ε1 − Ir1 and ε2 − Ir2
- Total: V = (ε1 + ε2) − I(r1 + r2)
- Compare with V = εeq − I req
εeq = ε1 + ε2, req = r1 + r2. If one cell is reversed, εeq = ε1 − ε2 but req still adds. For n identical cells: nε and nr, I = nε/(R + nr). Series is best when R is much larger than r.
Cells in parallel
Join all + terminals together and all − terminals together. Same V across both, currents add: I = I1 + I2.
- I1 = (ε1 − V)/r1, I2 = (ε2 − V)/r2
- Add and solve for V: V = (ε1r2 + ε2r1)/(r1 + r2) − I r1r2/(r1 + r2)
εeq = (ε1r2 + ε2r1)/(r1 + r2), req = r1r2/(r1 + r2). Handy form: εeq/req = ε1/r1 + ε2/r2. For n identical cells: ε and r/n. Parallel is best when R is much smaller than r.
Try it
In the 3D: open the switch and read V. Close it with R = 5 Ω and predict V before looking (ε = 6 V, r = 1 Ω). Then find the R that makes the green bar tallest.
At home (with an adult): in a car or bike with lights on, watch the headlight brightness when the engine is started. The dimming is the Ir drop of the battery.
Board exam focus
Derive equivalent emf and internal resistance for series and parallel (3–5 marks); V–I graph of a cell (straight line, slope −r, intercept ε); numericals on r, terminal voltage and power; difference between emf and terminal voltage.
Key formulas and definitions
- I = ε /(R + r)
- V = ε − Ir (discharging), V = ε + Ir (charging)
- r = (ε − V)/I = (ε/V − 1) R
- P = VI = I²R = V²/R, W = Pt
- Pmax in R when R = r: Pmax = ε²/4r
- Series: εeq = ε1 + ε2, req = r1 + r2
- Parallel: εeq = (ε1r2 + ε2r1)/(r1 + r2), req = r1r2/(r1 + r2)
Worked examples
1. A cell of emf 6 V and internal resistance 1 Ω is joined to a 5 Ω resistor. Find I and V.
Step 1: I = ε/(R + r) = 6/(5 + 1) = 1 A. Step 2: V = ε − Ir = 6 − 1 × 1 = 5 V. Check: V = IR = 5 V.
2. A cell reads 1.5 V on open circuit and 1.2 V when a 4 Ω resistor is joined. Find r.
Step 1: I = V/R = 1.2/4 = 0.3 A. Step 2: r = (ε − V)/I = 0.3/0.3. Answer: r = 1 Ω.
3. A 12 V battery with r = 0.5 Ω is charged by a current of 2 A. Terminal voltage during charging?
Step 1: while charging, V = ε + Ir. Step 2: V = 12 + 2 × 0.5 = 13 V.
4. A 1000 W heater runs 3 hours a day for 30 days. Units used and cost at ₹8 per unit?
Step 1: energy = 1 kW × 3 h × 30 = 90 kWh. Step 2: cost = 90 × 8 = ₹720.
5. A 220 V, 100 W bulb: find its resistance and the current it takes.
Step 1: R = V²/P = 220²/100 = 484 Ω. Step 2: I = P/V = 100/220 ≈ 0.45 A.
6. Three identical cells, each 2 V and 0.3 Ω, are in series with a 5.1 Ω resistor. Find the current.
Step 1: εeq = 3 × 2 = 6 V. Step 2: req = 3 × 0.3 = 0.9 Ω. Step 3: I = 6/(5.1 + 0.9) = 1 A.
7. Two cells, 4 V with 2 Ω and 2 V with 1 Ω, are in parallel (like terminals together). Find εeq and req.
Step 1: εeq = (ε1r2 + ε2r1)/(r1 + r2) = (4 × 1 + 2 × 2)/3 = 8/3 ≈ 2.67 V. Step 2: req = (2 × 1)/3 ≈ 0.67 Ω.
8. A cell of emf 6 V and r = 2 Ω. What R draws maximum power, and how much?
Step 1: maximum power when R = r = 2 Ω. Step 2: I = 6/(2 + 2) = 1.5 A. Step 3: P = I²R = 2.25 × 2 = 4.5 W (= ε²/4r = 36/8).
Common mistakes
- Calling emf a force. It is energy per unit charge, measured in volts.
- Forgetting r in I = ε/(R + r) when the question gives internal resistance.
- Using V = ε − Ir while the cell is being charged; then V = ε + Ir.
- Adding emfs of cells in parallel. For identical cells in parallel, the emf stays ε.