France Quatrième Physics-Chemistry
Chapters: 4
1. Matter and its changes
Particle model: molecules and atoms · Periodic table as a way to sort atoms · Chemical reactions: reactants, products, atoms conserved · Density as a property of a substance · Everyday combustions · Structure of the Universe
- Atoms and Molecules – In a chemical reaction mass is neither created nor destroyed (conservation of mass), and a compound always has its elements in the same ratio by mass (constant proportions). Dalton explained both: matter is made of tiny atoms that join in small whole numbers. Atoms join to form molecules; charged atoms or groups are ions. Formulae are written by crossing valencies. Molecular mass (or formula unit mass for ionic compounds) is the sum of the atomic masses in the formula, in u.
- Periodic Classification of Elements – Scientists sorted elements so that similar ones sit together. Döbereiner made triads, Newlands found that every 8th element repeats (octaves), Mendeleev arranged elements by atomic mass and left gaps for unknown ones. Moseley showed that atomic number is the real key. Modern periodic law: the properties of elements are a periodic function of their atomic numbers. The modern table has 7 periods and 18 groups. Elements with Z > 100 get temporary IUPAC names built from digit roots (nil, un, bi, tri, quad, pent, hex, sept, oct, enn) plus -ium.
- Chemical Reactions and Balancing Equations – In a chemical reaction atoms are not made or destroyed; they only change partners. So a chemical equation must have the same number of each kind of atom on both sides. We balance it by changing the numbers in front of formulas, never the formulas themselves.
- Density – Density tells how much mass is packed into each unit of volume: ρ = m ÷ V. Its SI unit is kg/m³; in the lab we often use g/cm³ (1 g/cm³ = 1000 kg/m³). Water has density 1 g/cm³. An object less dense than a liquid floats in it; a denser one sinks.
- Combustion – Combustion (burning) is a chemical change in which a fuel reacts fast with oxygen and gives out heat and light. It needs three things: fuel, oxygen and heat (to reach the ignition temperature). Remove any one and the fire goes out. With plenty of air, fuels that contain carbon and hydrogen burn completely to carbon dioxide and water (blue flame). With too little air, burning is incomplete and gives soot and poisonous carbon monoxide (yellow, smoky flame). Carbon dioxide turns limewater milky. The energy released by burning 1 g of a fuel is its calorific value.
2. Motion and interactions
Speed = distance / time · Interactions and forces
- Motion: Distance, Speed, Velocity, Acceleration and Graphs – An object is in motion when its position changes with time. Distance is the full path length (a scalar); displacement is the straight gap from start to finish with a direction (a vector). Speed = distance ÷ time; velocity = displacement ÷ time. Acceleration = change in velocity ÷ time. The slope of an s–t graph gives velocity, the slope of a v–t graph gives acceleration, and the area under a v–t graph gives the distance. For uniform acceleration: v = u + at, s = ut + ½at², v² = u² + 2as.
- Forces: Pushes and Pulls – A force is a push or a pull between two objects. It is measured in newtons (N). Contact forces need touching (push, friction, normal force, tension, buoyancy); non-contact forces act at a distance (gravity, magnetism, electric). A force is drawn as an arrow: start = point of application, direction, length = size. Forces can change an object's speed, direction or shape. If forces balance, a still object stays still (equilibrium). Forces always come in pairs: if A pushes B, B pushes A back equally (Newton's third law).
3. Energy
Series and parallel circuits: current and voltage laws · Resistance and Ohm’s law
- Electric Current, Potential Difference and Electric Circuits – Electric current is the rate of flow of charge, I = Q/t, measured in amperes with an ammeter joined in series. Potential difference is the work done to move a unit charge between two points, V = W/Q, measured in volts with a voltmeter joined in parallel. Charge flows only in a closed circuit.
- Ohm's Law – At constant temperature, the current through a conductor is directly proportional to the potential difference across it: V = I × R. R is the resistance, measured in ohms (Ω); 1 Ω = 1 V/1 A. The V–I graph of an ohmic conductor is a straight line through the origin.
4. Signals
Light: straight-line travel, speed, light-year · Sound: propagation, speed, frequency
- Refraction of Light: Laws, Refractive Index and the Glass Slab – Light changes speed when it goes from one transparent medium to another, and so it bends at the boundary (unless it hits along the normal). Going into an optically denser medium it slows down and bends toward the normal; coming out it speeds up and bends away. For a pair of media, sin i / sin r stays constant (Snell's law); this constant is the refractive index, which also equals the ratio of the speeds of light, n = c/v. In a rectangular glass slab the emergent ray is parallel to the incident ray but shifted sideways (lateral displacement).
- Sound – Sound is made by vibrating objects. It travels through a medium (air, water, solids) as a longitudinal wave: particles move back and forth, making crowded parts (compressions) and spread-out parts (rarefactions). Frequency (Hz) sets the pitch, amplitude sets the loudness, and speed v = f × λ. Sound cannot travel in vacuum. Humans hear 20 Hz to 20,000 Hz; below is infrasound, above is ultrasound. Reflected sound gives echoes, used and controlled in buildings.