Germany Jahrgangsstufe 13 Chemistry

Chapters: 5

1. How chemists think and work

Chemistry subject knowledge · Scientific inquiry in chemistry · Communicating chemistry · Evaluating chemistry issues

The Scientific Method – The scientific method is the careful way scientists find out how the world works. Observe something, ask a testable question, make a hypothesis (a clear, testable guess), test it with a fair experiment (change one variable, measure one, keep the rest the same), repeat and record data, analyse it, draw a conclusion and share it so others can check. Results that fail the test are useful too: they send you back to a new hypothesis.
Research Skills: From a Question to a Finished Project – Research is a careful way of finding an answer. You ask a clear, focused question, plan how to answer it, find information and check that each source can be trusted, collect and analyse your own data, draw a conclusion that the evidence supports, and share it while crediting every source you used.

Colour and dyes

Colour and Dyes – A substance looks coloured because its molecules absorb some colours of white light and the rest reaches the eye. The absorbed light lifts an electron across the HOMO-LUMO gap. A longer chain of alternating double bonds makes the gap smaller, so the dye absorbs longer wavelengths. You see the complementary colour. Dyes dissolve; pigments stay as solid grains.

Acid-base equilibria

Ionic Equilibrium: Acids, Bases, Ionisation and pH – Acids and bases can be defined in three ways: Arrhenius (give H⁺ or OH⁻ in water), Brønsted–Lowry (proton donor or acceptor) and Lewis (electron-pair acceptor or donor). Strong acids and bases ionise fully; weak ones ionise only a little and set up an equilibrium with constant Ka or Kb. Water itself ionises: Kw = [H⁺][OH⁻] = 1.0 × 10⁻¹⁴ at 25 °C. pH = −log[H⁺] and pH + pOH = 14. For a weak electrolyte, α ≈ √(K/C), so dilution increases α (Ostwald's dilution law). For a conjugate pair, Ka × Kb = Kw. Salts of weak acids or weak bases react with water (hydrolysis) and give non-neutral solutions.

From amino acids to proteins · Synthetic polymers and plastics

Proteins and Enzymes: Amino Acids, Peptide Bond, Structure and Denaturation – Proteins are long chains of amino acids. Each amino acid has an amino group (–NH₂), an acid group (–COOH), a hydrogen and a side group R on one carbon. The –COOH of one amino acid joins the –NH₂ of the next, losing water, to make a peptide bond (–CO–NH–). The order of amino acids is the primary structure; coils and sheets are the secondary structure; the full 3D fold is the tertiary structure; several chains together make the quaternary structure. Heat, acid or alcohol can undo the folds (denaturation). Enzymes are mostly proteins that speed up reactions in the body.
Polymers – A polymer is a giant molecule made by joining many small molecules (monomers) into a long chain. In addition polymerisation, monomers with a C=C double bond open up and link with nothing lost (ethene → poly(ethene)). In condensation polymerisation, two kinds of monomer with reactive groups at both ends join and give off a small molecule such as water at every link (nylon, polyester). Nature makes polymers too: starch, cellulose, proteins, DNA, rubber. Separate chains give thermoplastics that melt and can be recycled; cross-linked chains give thermosets that never melt. Most plastics do not rot, so we must reduce, reuse and recycle them.

Energy and sustainability

Minerals and Energy Resources – Minerals are natural substances found in rocks. They are metallic (ferrous or non-ferrous), non-metallic, or energy minerals. Energy comes from conventional sources like coal, petroleum, natural gas and electricity, and from non-conventional sources like sun, wind, nuclear, biogas, tides and heat from the Earth. Both minerals and energy must be conserved.