Forms of energy in processes
In a chemical process energy changes form. Chemical energy stored in bonds can become heat, light, electrical or movement energy. For example, burning petrol gives heat, the engine turns part of it to movement, and the exhaust and engine carry away the rest as heat.
The law of conservation of energy says: the total stays the same. Nothing is created or lost.
What is energy quality?
Quality of energy means how well it can be used to do useful work.
- High quality: concentrated and ordered, such as fuel, food, a charged battery, sunlight, or heat at a very high temperature.
- Low quality: spread out and disordered, such as warm air or lukewarm water at the same temperature as the surroundings.
The same amount of energy can be high or low quality. A bucket of boiling water and a lake at 25 degrees can hold the same energy, but only the first can run an engine.
Energy degradation
Energy degradation means energy changes from high quality to low quality. Every real process does it: friction, burning, a hot cup cooling, a bulb glowing. The energy spreads into surroundings and cannot be gathered back without more work and more high-quality energy.
This is why a perpetual motion machine cannot exist and why we say "we use up" energy, even though the total never changes. What we really use up is quality.
Efficiency of conversions
Efficiency = useful energy out / energy in x 100%.
Every conversion produces some low-quality heat, so efficiency is always below 100%. Examples: electric motor 80 to 95%, LED lamp about 40%, petrol engine 25 to 30%, power station 35 to 45%.
For a heat engine, the best possible efficiency depends only on the two temperatures (in kelvin): maximum efficiency = 1 - T(cold) / T(hot). A hotter source gives a higher limit. The cold side is usually the surroundings, about 300 K (27 degrees C). Convert: K = degrees C + 273.
Try it: hot cup vs warm bath
Pour hot water into a small cup and warm water into a big bucket. Touch both. Which could heat a cold spoon quickly? The bucket may hold more total energy, but the cup has higher-quality energy. In step 5, slide the source temperature and see the best possible efficiency change.
Key formulas and definitions
- Efficiency = (useful energy out / energy in) x 100%
- Max efficiency = 1 - T(cold) / T(hot) (temperatures in K)
- K = degrees C + 273
Worked examples
1. A machine takes in 500 J and gives 150 J of useful work. Find the efficiency and the wasted energy.
Efficiency = 150 / 500 x 100 = 30%. Wasted = 500 - 150 = 350 J, mostly as low-quality heat.
2. A heat source is at 600 K and the surroundings at 300 K. What is the best possible efficiency?
1 - 300/600 = 1 - 0.5 = 0.5, so 50%.
3. Source at 127 degrees C, surroundings at 27 degrees C. Best efficiency?
T(hot) = 400 K, T(cold) = 300 K. 1 - 300/400 = 0.25 = 25%.
Common mistakes
- Saying energy is "used up" and disappears. The total stays the same; only the quality falls.
- Using degrees C in 1 - Tc/Th. You must use kelvin.
- Thinking more total energy always means more useful energy. A lake holds lots of energy but is low quality.
- Thinking 100% efficiency is possible with better engineering. Some heat always escapes.